Categories: Science

Ammonia stress controls colloidal steel nitride synthesis in molten salts

This web page was created programmatically, to learn the article in its authentic location you may go to the hyperlink bellow:
https://www.nature.com/articles/s41586-026-10801-3
and if you wish to take away this text from our website please contact us


  • Nakamura, S., Mukai, T. & Senoh, M. Candela-class high-brightness InGaN/AlGaN double-heterostructure blue-light-emitting diodes. Appl. Phys. Lett. 64, 1687–1689 (1994).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Amano, H. et al. The 2018 GaN energy electronics roadmap. J. Phys. D Appl. Phys. 51, 163001 (2018).

    Article 
    ADS 

    Google Scholar
     

  • Höhn, P. & Niewa, R. in Handbook of Solid State Chemistry Part 1 (eds Dronskowski, R. et al.) 251–359 (Wiley, 2017).

  • Sun, W. et al. A map of the inorganic ternary steel nitrides. Nat. Mater. 18, 732–739 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Gao, Z. et al. Shielding Pt/γ-Mo2N by inert nano-overlays allows secure H2 manufacturing. Nature 638, 690–696 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Hashimoto, T., Wu, F., Speck, J. S. & Nakamura, S. A GaN bulk crystal with improved structural high quality grown by the ammonothermal methodology. Nat. Mater. 6, 568–571 (2007).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, D. et al. Ferroelectric YAlN grown by molecular beam epitaxy. Appl. Phys. Lett. 123, 033504 (2023).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Skidmore, C. H. et al. Proximity ferroelectricity in wurtzite heterostructures. Nature 637, 574–579 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Talley, Okay. R. et al. Synthesis of LaWN3 nitride perovskite with polar symmetry. Science 374, 1488–1491 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Kuykendall, T., Ulrich, P., Aloni, S. & Yang, P. Complete composition tunability of InGaN nanowires utilizing a combinatorial method. Nat. Mater. 6, 951–956 (2007).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Fix, R., Gordon, R. G. & Hoffman, D. M. Chemical vapor deposition of titanium, zirconium, and hafnium nitride skinny movies. Chem. Mater. 3, 1138–1148 (1991).

    Article 
    CAS 

    Google Scholar
     

  • Fix, R., Gordon, R. G. & Hoffman, D. M. Chemical vapor deposition of vanadium, niobium, and tantalum nitride skinny movies. Chem. Mater. 5, 614–619 (1993).

    Article 
    CAS 

    Google Scholar
     

  • Parvizian, M. & De Roo, J. Precursor chemistry of steel nitride nanocrystals. Nanoscale 13, 18865–18882 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Yang, L. et al. Cation alternate in colloidal transition steel nitride nanocrystals. J. Am. Chem. Soc. 146, 12556–12564 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Vaughn, D. D. II et al. Solution synthesis of Cu3PdN nanocrystals as ternary steel nitride electrocatalysts for the oxygen discount response. Chem. Mater. 26, 6226–6232 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Shanker, G. S. & Ogale, S. Faceted colloidal metallic Ni3N nanocrystals: size-controlled solution-phase synthesis and electrochemical total water splitting. ACS Appl. Energy Mater. 4, 2165–2173 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Taylor, P. N. et al. Synthesis of extensively tunable and extremely luminescent zinc nitride nanocrystals. J. Mater. Chem. C 2, 4379–4382 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Talapin, D. V., Lee, J.-S., Kovalenko, M. V. & Shevchenko, E. V. Prospects of colloidal nanocrystals for digital and optoelectronic functions. Chem. Rev. 110, 389–458 (2010).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • García de Arquer, F. P. et al. Semiconductor quantum dots: technological progress and future challenges. Science 373, eaaz8541 (2021).

    Article 
    PubMed 

    Google Scholar
     

  • Wang, H. et al. Transition steel nitrides for electrochemical vitality functions. Chem. Soc. Rev. 50, 1354–1390 (2021).

    Article 
    PubMed 

    Google Scholar
     

  • Xu, X. et al. Two-dimensional arrays of transition steel nitride nanocrystals. Adv. Mater. 31, 1902393 (2019).

    Article 

    Google Scholar
     

  • Guy, Okay. et al. Original synthesis of molybdenum nitrides utilizing steel cluster compounds as precursors: functions in heterogeneous catalysis. Chem. Mater. 32, 6026–6034 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Karaballi, R. A., Humagain, G., Fleischman, B. R. A. & Dasog, M. Synthesis of plasmonic group-4 nitride nanocrystals by solid-state metathesis. Angew. Chem. Int. Ed. 58, 3147–3150 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Giordano, C., Erpen, C., Yao, W., Mike, B. & Antonietti, M. Metal nitride and steel carbide nanoparticles by a comfortable urea pathway. Chem. Mater. 21, 5136–5144 (2009).

    Article 
    CAS 

    Google Scholar
     

  • Murray, C. B., Norris, D. J. & Bawendi, M. G. Synthesis and characterization of almost monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites. J. Am. Chem. Soc. 115, 8706–8715 (1993).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Yin, Y. & Alivisatos, A. P. Colloidal nanocrystal synthesis and the natural–inorganic interface. Nature 437, 664–670 (2005).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Dean, J. A. Lange’s Handbook of Chemistry fifteenth edn (McGraw-Hill, 1999).

  • Zhang, H. et al. Stable colloids in molten inorganic salts. Nature 542, 328–331 (2017).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, Z. et al. Colloidal chemistry in molten inorganic salts: direct synthesis of III–V quantum dots by way of dehalosilylation of (Me3Si)3Pn (Pn = P, As) with group III halides. J. Am. Chem. Soc. 147, 9198–9209 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Ondry, J. C. et al. Reductive pathways in molten inorganic salts allow colloidal synthesis of III-V semiconductor nanocrystals. Science 386, 401–407 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Portehault, D. et al. A common answer route towards steel boride nanocrystals. Angew. Chem. Int. Ed. 50, 3262–3265 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Liu, X., Fechler, N. & Antonietti, M. Salt soften synthesis of ceramics, semiconductors and carbon nanostructures. Chem. Soc. Rev. 42, 8237–8265 (2013).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Guan, H. et al. General molten-salt path to three-dimensional porous transition steel nitrides as delicate and secure Raman substrates. Nat. Commun. 12, 1376 (2021).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Cho, W., Zhou, Z., Lin, R., Ondry, J. C. & Talapin, D. V. Synthesis of colloidal GaN and AlN nanocrystals in biphasic molten salt/natural solvent mixtures beneath high-pressure ammonia. ACS Nano 17, 1315–1326 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Cassidy, J. et al. Ammoniate intermediates allow tunable biphasic molten salt/natural synthesis of colloidal GaN nanocrystals. Chem. Mater. 38, 4017–4028 (2026).

    Article 
    CAS 

    Google Scholar
     

  • Parvizian, M. et al. Molten salt-assisted synthesis of titanium nitride. Small Methods 8, 2400228 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Jacobs, Okay., Zaziski, D., Scher, E. C., Herhold, A. B. & Paul Alivisatos, A. Activation volumes for solid-solid transformations in nanocrystals. Science 293, 1803–1806 (2001).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Hendricks, M. P., Campos, M. P., Cleveland, G. T., Plante, I.J.-L. & Owen, J. S. A tunable library of substituted thiourea precursors to steel sulfide nanocrystals. Science 348, 1226–1230 (2015).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Allulli, S. Solubilities of ammonia in alkali nitrate and perchlorate melts. J. Phys. Chem. 73, 1084–1087 (1969).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Jolly, W. A. Heats, free energies, and entropies in liquid ammonia. Chem. Rev. 50, 351–361 (1952).

    Article 
    CAS 

    Google Scholar
     

  • Takekawa, N. et al. GaN development by way of tri-halide vapor part epitaxy utilizing stable supply of GaCl3: investigation of the expansion dependence on NH3 and extra Cl2. Jpn. J. Appl. Phys. 58, SC1022 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Nakamura, S., Mukai, T., Senoh, M. & Iwasa, N. Thermal annealing results on p-type Mg-doped GaN movies. Jpn. J. Appl. Phys. 31, L139 (1992).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Jain, S. C., Willander, M., Narayan, J. & Van Overstraeten, R. III–nitrides: development, characterization, and properties. J. Appl. Phys. 87, 965–1006 (2000).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Yu, Okay. M. et al. Effects of native defects on properties of low temperature grown, non- stoichiometric gallium nitride. J. Phys. D Appl. Phys. 48, 385101 (2015).

    Article 
    ADS 

    Google Scholar
     

  • Hubáček, T., Hospodková, A., Oswald, J., Kuldova, Okay. & Pangrác, J. Improvement of luminescence properties of GaN buffer layer for quick nitride scintillator buildings. J. Cryst. Growth 464, 221–225 (2017).

    Article 
    ADS 

    Google Scholar
     

  • Guler, U., Shalaev, V. M. & Boltasseva, A. Nanoparticle plasmonics: going sensible with transition steel nitrides. Mater. Today 18, 227–237 (2015).

    Article 
    CAS 

    Google Scholar
     

  • Tsai, M.-F. et al. Au nanorod design as light-absorber within the first and second organic near-infrared home windows for in vivo photothermal remedy. ACS Nano 7, 5330–5342 (2013).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • van Hove, R. P., Sierevelt, I. N., van Royen, B. J. & Nolte, P. A. Titanium-nitride coating of orthopaedic implants: a evaluation of the literature. BioMed Res. Int. 2015, 485975 (2015).

    PubMed 
    PubMed Central 

    Google Scholar
     

  • Yan, R. et al. GaN/NbN epitaxial semiconductor/superconductor heterostructures. Nature 555, 183–189 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zolotavin, P. & Guyot-Sionnest, P. Meissner impact in colloidal Pb nanoparticles. ACS Nano 4, 5599–5608 (2010).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations utilizing a plane-wave foundation set. Phys. Rev. B 54, 11169–11186 (1996).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Perdew, J. P., Burke, Okay. & Ernzerhof, M. Generalized gradient approximation made easy. Phys. Rev. Lett. 77, 3865–3868 (1996).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave methodology. Phys. Rev. B 59, 1758–1775 (1999).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Grimme, S., Antony, J., Ehrlich, S. & Krieg, H. A constant and correct ab initio parametrization of density practical dispersion correction (DFT-D) for the 94 components H-Pu. J. Chem. Phys. 132, 154104 (2010).

    Article 
    ADS 
    PubMed 

    Google Scholar
     

  • Nosé, S. A unified formulation of the fixed temperature molecular dynamics strategies. J. Chem. Phys. 81, 511–519 (1984).

    Article 
    ADS 

    Google Scholar
     

  • Khudorozhkova, A. O., Isakov, A. V., Kataev, A. A., Red’kin, A. A. & Zaikov, Y. P. Density of KF–OkayCl–KI melts. Russ. Metall. 2020, 918–924 (2020).

    Article 
    ADS 

    Google Scholar
     

  • Khokhar, V. & Jiang, D.-e. Ammonia stress controls colloidal steel nitride synthesis in molten salts – DFT buildings and AIMD simulation trajectories. Zenodo (2026).


  • This web page was created programmatically, to learn the article in its authentic location you may go to the hyperlink bellow:
    https://www.nature.com/articles/s41586-026-10801-3
    and if you wish to take away this text from our website please contact us

    fooshya

    Share
    Published by
    fooshya

    Recent Posts

    Engineer identifies and explains each ’90s laptop seen in Jurassic Park

    This web page was created programmatically, to learn the article in its authentic location you…

    8 minutes ago

    [Form 4] Atour Lifestyle Holdings Ltd Insider Trading Activity

    This web page was created programmatically, to learn the article in its unique location you…

    17 minutes ago

    Alienware 15: 7 Causes It’s A Critical Gaming Laptop: Video games and Devices Listicle

    This web page was created programmatically, to learn the article in its authentic location you'll…

    31 minutes ago

    Tips on how to defend your sensible residence devices in a heatwave — 3 knowledgeable tricks to do proper now

    This web page was created programmatically, to learn the article in its unique location you…

    53 minutes ago

    Tulalip Tribes of Washington attain tentative settlement with Gambling Commission on proposed gaming compact modification

    This web page was created programmatically, to learn the article in its authentic location you'll…

    59 minutes ago

    Garmin removes recent CIRQA reference from help web page

    This web page was created programmatically, to learn the article in its authentic location you…

    1 hour ago